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Catalysis Series
Vanadium Catalysis
Edited by
Manas Sutradhar;
Manas Sutradhar
University of Lisbon, Portugal
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Armando J L Pombeiro;
Armando J L Pombeiro
University of Lisbon, Portugal
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José Armando L da Silva
José Armando L da Silva
University of Lisbon, Portugal
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Hardback ISBN:
978-1-78801-857-9
PDF ISBN:
978-1-83916-088-2
EPUB ISBN:
978-1-83916-089-9
Special Collection:
2020 ebook collection
Series:
Catalysis Series
No. of Pages:
588
Published online:
05 Nov 2020
Published in print:
12 Nov 2020
Book Chapter
Chapter 25: Vanadium Catalysis Relevant to Nitrogenase
By
Hung-Ruei Pan
;
Hung-Ruei Pan
Department of Chemistry, National Cheng Kung University
No.1, University Road
Tainan City 701
Taiwan
[email protected]
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Hua-Fen Hsu
Hua-Fen Hsu
Department of Chemistry, National Cheng Kung University
No.1, University Road
Tainan City 701
Taiwan
[email protected]
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Published:05 Nov 2020
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Special Collection: 2020 ebook collectionSeries: Catalysis Series
Page range:
564 - 576
Citation
H. Pan and H. Hsu, in Vanadium Catalysis, ed. M. Sutradhar, A. J. L. Pombeiro, and J. A. L. da Silva, The Royal Society of Chemistry, 2020, ch. 25, pp. 564-576.
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This chapter focuses on vanadium nitrogenase and vanadium complexes showing catalytic reactivity relevant to nitrogenase. The structural and catalytic features of the protein are described. Examples of synthetic vanadium complexes serving as catalysts for (1) dinitrogen reduction to ammonia, (2) silylation of N2 into silylamine and (3) reduction and disproportionation of N2H4 into NH3 are documented.
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