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Vanadium catalysts, among the most important ones, display unique characteristics in olefin polymerization, namely in the preparation of amorphous polymers in ethylene/propylene/non-conjugated diene copolymerization, syndiotactic polypropylene in propylene polymerization and polyethylene with high-molecular weight. In this chapter, the efficient vanadium catalysts with various ligands for olefin oligomerization, polymerization and copolymerization will be introduced in detail.

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