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Theoretical and Computational Chemistry Series
Effects of Electric Fields on Structure and Reactivity: New Horizons in Chemistry
Edited by
Sason Shaik;
Sason Shaik
The Hebrew University of Jerusalem, Israel
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Thijs Stuyver
Thijs Stuyver
The Hebrew University of Jerusalem, Israel
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Hardback ISBN:
978-1-83916-169-8
PDF ISBN:
978-1-83916-304-3
EPUB ISBN:
978-1-83916-305-0
Special Collection:
2021 ebook collection
No. of Pages:
428
Published online:
05 Mar 2021
Published in print:
18 Mar 2021
Book Chapter
CHAPTER 3: Experimentally Harnessing Electric Fields in Chemical Transformations
By
S. Ciampi
;
S. Ciampi
School of Molecular and Life Sciences, Curtin Institute of Functional Molecules and Interfaces, Curtin University
Bentley
Western Australia
Australia
[email protected][email protected]
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I. Diez-Perez
;
I. Diez-Perez
Department of Chemistry, Faculty of Natural & Mathematical Sciences, King's College London
Britannia House, 7 Trinity Street
London SE1 1DB
UK
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M. L. Coote
;
M. L. Coote
ARC Centre of Excellence for Electromaterials Science, Research School of Chemistry, Australian National University
Canberra
Australian Capital Territory
Australia
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N. Darwish
N. Darwish
School of Molecular and Life Sciences, Curtin Institute of Functional Molecules and Interfaces, Curtin University
Bentley
Western Australia
Australia
[email protected][email protected]
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Published:05 Mar 2021
-
Special Collection: 2021 ebook collection
Page range:
71 - 118
Citation
S. Ciampi, I. Diez-Perez, M. L. Coote, and N. Darwish, in Effects of Electric Fields on Structure and Reactivity
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This chapter outlines experiments in which electric fields have been demonstrated to drive reaction rates and selectivity. The purpose of the chapter is to introduce seemingly unrelated experimental platforms – from an electrified nanoscale gap of a scanning tunnelling microscope, to the air–water interface of a microscale droplet – that can be used to harness electrostatic effects on bonding and reactivity.
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