Gibbs Energy and Helmholtz Energy: Liquids, Solutions and Vapours
CHAPTER 5: Simultaneous Determination of Equilibrium Constants, Enthalpy Changes and Stoichiometries by Titration Calorimetry
Published:08 Sep 2021
L. D. Hansen, M. K. Transtrum, and J. D. Kenealey, in Gibbs Energy and Helmholtz Energy: Liquids, Solutions and Vapours, ed. E. Wilhelm and T. M. Letcher, The Royal Society of Chemistry, 2021, pp. 205-226.
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This chapter reviews the history, key developments in instrumentation and data analysis and representative applications of titration calorimetry to the simultaneous determination of equilibrium constants, enthalpy changes and stoichiometries for reactions in solution. Statistical methods for error analysis and optimizing operating conditions are developed and illustrated. Examples of applications of titration calorimetric methods to solve problems in biophysics are presented.