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Gibbs Energy and Helmholtz Energy: Liquids, Solutions and Vapours
Edited by
Emmerich Wilhelm;
Emmerich Wilhelm
University of Vienna, Austria
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Trevor M Letcher
Trevor M Letcher
University of KwaZuluNatal, South Africa
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Hardback ISBN:
978-1-83916-201-5
PDF ISBN:
978-1-83916-409-5
EPUB ISBN:
978-1-83916-410-1
Special Collection:
2021 ebook collection
No. of Pages:
486
Publication date:
08 Sep 2021
Book Chapter
CHAPTER 5: Simultaneous Determination of Equilibrium Constants, Enthalpy Changes and Stoichiometries by Titration Calorimetry
By
Jason D. Kenealey
Jason D. Kenealey
Department of Nutrition, Dietetics and Food Science, Brigham Young University
Provo
UT 84602
USA
[email protected]
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Published:08 Sep 2021
-
Special Collection: 2021 ebook collection
Page range:
205 - 226
Citation
L. D. Hansen, M. K. Transtrum, and J. D. Kenealey, in Gibbs Energy and Helmholtz Energy: Liquids, Solutions and Vapours, ed. E. Wilhelm and T. M. Letcher, The Royal Society of Chemistry, 2021, pp. 205-226.
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This chapter reviews the history, key developments in instrumentation and data analysis and representative applications of titration calorimetry to the simultaneous determination of equilibrium constants, enthalpy changes and stoichiometries for reactions in solution. Statistical methods for error analysis and optimizing operating conditions are developed and illustrated. Examples of applications of titration calorimetric methods to solve problems in biophysics are presented.
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