CHAPTER 7: Calculation Itinerary to Check the Quality of Vapour–Liquid Equilibrium Data
Published:08 Sep 2021
L. Fernández, J. Ortega, I. Gascón, C. Lafuente, and J. Wisniak, in Gibbs Energy and Helmholtz Energy: Liquids, Solutions and Vapours, ed. E. Wilhelm and T. M. Letcher, The Royal Society of Chemistry, 2021, pp. 238-268.
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This chapter presents a methodology to assess the quality of experimental vapour–liquid equilibrium data for binary systems through so-called thermodynamic consistency tests. Several methods that have been described in the literature and a new contribution made by the authors are presented together with a description of each method. These methods were applied to several binary systems extracted from the literature in order to assess their quality and draw conclusions. A practical example is carried out on unpublished experimental data for a binary system.