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Green Chemistry Series
Sustainable and Functional Redox Chemistry
Edited by
Shinsuke Inagi
Shinsuke Inagi
Tokyo Insititute of Technology, Japan
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Hardback ISBN:
978-1-83916-246-6
PDF ISBN:
978-1-83916-482-8
EPUB ISBN:
978-1-83916-483-5
Special Collection:
2022 ebook collection
Series:
Green Chemistry
No. of Pages:
386
Publication date:
29 Apr 2022
Book Chapter
Chapter 9: Bioinspired Catalyst Learned from B12-dependent Enzymes
By
HISASHI Shimakoshi
HISASHI Shimakoshi
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
Nishi-ku, Motooka 744
Fukuoka 819-0395
Japan
[email protected]
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Published:29 Apr 2022
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Special Collection: 2022 ebook collectionSeries: Green Chemistry
Page range:
207 - 226
Citation
H. Shimakoshi, in Sustainable and Functional Redox Chemistry, ed. S. Inagi, The Royal Society of Chemistry, 2022, ch. 9, pp. 207-226.
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In this chapter, a bioinspired catalyst design for organic reactions is described. Photochemical redox reactions well catalyzed by the bioinspired metal complex are summarized. As metal enzymes catalyze various molecular transformations that are of particular interest from the viewpoint of biological chemistry as well as synthetic organic chemistry, unique bioorganometallic B12 enzyme-inspired reactions, such as dehalogenation, hydrogen production, alkene reductions, and cross-coupling reactions, have been developed.
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