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Coordination Chemistry Fundamentals
Organometallic Chemistry
Edited by
Hiroshi Nakazawa;
Hiroshi Nakazawa
Osaka Metropolitan University, Japan
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Julian Koe
Julian Koe
International Christian University, Japan
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Hardback ISBN:
978-1-83916-406-4
PDF ISBN:
978-1-83916-420-0
EPUB ISBN:
978-1-83916-421-7
Special Collection:
2021 ebook collection
No. of Pages:
284
Publication date:
09 Jul 2021
Book Chapter
Chapter 11: Chemistry of Transition Metal Complexes with Group 16 Elements: Transition Metal Complexes with Two Lone Pairs of Electrons on the Coordinating Atom
By
Kohtaro Osakada
Kohtaro Osakada
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Published:09 Jul 2021
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Special Collection: 2021 ebook collection
Page range:
203 - 227
Citation
K. Osakada, in Organometallic Chemistry, ed. H. Nakazawa and J. Koe, The Royal Society of Chemistry, 2021, ch. 11, pp. 203-227.
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The synthesis, bonding and properties of metal complexes with ligating Group 16 atoms O and S are discussed in this chapter. Despite the high electronegativity of these elements, M–OR and M–SR complexes show properties more consistent with coordination bonds of covalent character. Typical reactions such as the insertion of small molecules into M–O and M–S bonds, and coupling of thiolate ligands with organic ligands are presented.
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