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The use of immobilised chelating ligands for the high-performance separation of metal ions can be exploited in a variety of ways, including techniques based upon solvent partition. This Chapter briefly reviews two powerful techniques which have received significant attention in recent years and continue to gain application in the field of metal ion separations. The principles and practice of high-performance extraction chromatography and high-speed counter-current chromatography using chelating ligands will be discussed here, as both are closely related techniques to HPCIC.

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