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Catalysis Series
Organocatalytic Dynamic Kinetic Resolution
By
Hélène Pellissier
Hélène Pellissier
CNRS, France
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Hardback ISBN:
978-1-83916-565-8
PDF ISBN:
978-1-83916-635-8
EPUB ISBN:
978-1-83916-636-5
Special Collection:
2022 ebook collection
Series:
Catalysis Series
No. of Pages:
158
Publication date:
06 May 2022
Book Chapter
Chapter 8: Dynamic Kinetic Resolutions Promoted by Tetramisole Catalysts
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Published:06 May 2022
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Special Collection: 2022 ebook collectionSeries: Catalysis Series
Page range:
134 - 140
Citation
Organocatalytic Dynamic Kinetic Resolution, The Royal Society of Chemistry, 2022, ch. 8, pp. 134-140.
Download citation file:
This chapter is dedicated to dynamic kinetic resolutions promoted by tetramisole catalysts. Since their first application in 2006 in asymmetric organocatalysis by Birman, chiral cyclic isothioureas have been shown to be capable of promoting asymmetric transformations of different types evolving through dynamic kinetic resolution. Indeed, enantioselectivities of up to 99% ee have been reported in esterifications and alcoholytic ring-opening reactions using tetramisole or benzotetramisole as promoters.
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