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Catalysis Series
Organocatalytic Dynamic Kinetic Resolution
By
Hélène Pellissier
Hélène Pellissier
CNRS, France
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Hardback ISBN:
978-1-83916-565-8
PDF ISBN:
978-1-83916-635-8
EPUB ISBN:
978-1-83916-636-5
Special Collection:
2022 ebook collection
Series:
Catalysis Series
No. of Pages:
158
Publication date:
06 May 2022
Book Chapter
Chapter 5: Dynamic Kinetic Resolutions Promoted by N-Heterocyclic Carbene Catalysts
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Published:06 May 2022
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Special Collection: 2022 ebook collectionSeries: Catalysis Series
Page range:
96 - 111
Citation
Organocatalytic Dynamic Kinetic Resolution, The Royal Society of Chemistry, 2022, ch. 5, pp. 96-111.
Download citation file:
This chapter is dedicated to dynamic kinetic resolutions promoted by chiral N-heterocyclic carbenes, which have emerged over the last few decades as some of the most important organocatalysts. Although significant progress has been made in this field, examples of these transformations remain rare. However, this chapter shows that excellent enantioselectivities of up to 98% ee have been achieved in different types of reactions, such as benzoin condensations, domino reactions and transesterifications.
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