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Electrolytes, Interfaces and Interphases
By
Hardback ISBN:
978-1-83916-310-4
EPUB ISBN:
978-1-83916-617-4
PDF ISBN:
978-1-83767-131-1
No. of Pages:
800
Publication date:
12 Apr 2023
Book Chapter
Chapter 5: Ion Transport in Electrolytes
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Published:12 Apr 2023
Page range:
65 - 130
Citation
2023. "Ion Transport in Electrolytes", Electrolytes, Interfaces and Interphases, Kang Xu
Download citation file:
In this chapter, we allow static ions to move, and define a few basic transport properties: diffusion, migration, random motion of ions and solvent molecules, ambipolar diffusion of ions and counterions, and their correlation with the electrolyte viscosity and conductivity. The mathematical foundation to describe the ion movement is set: Fick’s laws, the multiple Einstein equations and the preliminary treatment of ion transport by Onsager using the Debye–Hückel model. The uniqueness of proton transport is discussed.
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Electrolytes, Interfaces and Interphases
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