Dienamine Catalysis for Organic Synthesis
In the past decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis.
High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis.
Building on the momentum of this rapidly expanding research area, Dienamine Catalysis for Organic Synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.
K. Anebouselvy, D. B. Ramachary, and I. Kumar, Dienamine Catalysis for Organic Synthesis, The Royal Society of Chemistry, 2018.
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Introduction to Dienamine Chemistryp1-9ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 2: Synthesis and Applications of Preformed Dienaminesp10-23ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 3: Barbas Dienamines (2-Aminobuta-1,3-Dienes): Scope and Applicationsp24-52ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 4: Ramachary’s Dienamines (Push–Pull Dienamines): In situ Generation and Applicationsp53-64ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 5: Serebryakov–Jørgensen Dienamines (1-Aminobuta-1,3-Dienes): Different In situ Generation Methods and Applications in [4+2]-Cycloadditionsp65-95ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 6: Serebryakov–Jørgensen Dienamines (1-Aminobuta-1,3-Dienes): Different In situ Generation Methods and Applications in [2+2], [3+2] and a Few Other Cycloadditionsp96-111ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 7: Asymmetric α-Selective and Remote γ-Selective Functionalization of Enals and Enones Through Serebryakov–Jørgensen Dienamines (1-Aminobuta-1,3-Dienes)p112-135ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 8: Applications of Serebryakov–Jørgensen Dienamines (1-Aminobuta-1,3-Dienes) in Domino or Cascade Reactionsp136-149ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 9: Aminoenyne (2-Aminobuta-1,3-Enyne) Catalysis: In situ Generation and Synthetic Applications in Organic Reactionsp150-157ByKengadarane Anebouselvy;Kengadarane AnebouselvyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 10: Trienamine-catalyzed Stereoselective Cycloadditions and Other Remote Functionalizations of Polyconjugated Enals/Enonesp158-193ByIndresh Kumar;Indresh KumarDepartment of Chemistry, Birla Institute of Technology and Science-PilaniPilani Campus333 031 RajasthanIndiaindresh.kumar@pilani.bits-pilani.ac.in indresh.chemistry@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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CHAPTER 11: Tetraenamine-catalyzed Stereoselective Cycloadditions of Polyunsaturated Carbonyl Compoundsp194-198ByIndresh Kumar;Indresh KumarDepartment of Chemistry, Birla Institute of Technology and Science-Pilani, Pilani Campus333 031 RajasthanIndiaindresh.kumar@pilani.bits-pilani.ac.in indresh.chemistry@gmail.comSearch for other works by this author on:Dhevalapally B. RamacharyDhevalapally B. RamacharyUniversity of Hyderabad, School of Chemistry, Catalysis LaboratoryHyderabad500 046Indiaramsc@uohyd.ac.in ramchary.db@gmail.comSearch for other works by this author on:
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