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Catalysis Series
Enantioselective Cobalt-catalysed Transformations
By
Hélène Pellissier
Hélène Pellissier
CNRS, France
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Hardback ISBN:
978-1-78801-462-5
PDF ISBN:
978-1-78801-509-7
EPUB ISBN:
978-1-78801-515-8
Special Collection:
2018 ebook collection
Series:
Catalysis Series
No. of Pages:
224
Publication date:
15 Aug 2018
Book Chapter
CHAPTER 8: Synthesis of Chiral Acyclic Compounds Through Enantioselective Cobalt-catalysed 1,2-Nucleophilic Additions to Carbonyl Compounds and Derivatives
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Published:15 Aug 2018
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Special Collection: 2018 ebook collectionSeries: Catalysis Series
Page range:
178 - 187
Citation
Enantioselective Cobalt-catalysed Transformations, The Royal Society of Chemistry, 2018, pp. 178-187.
Download citation file:
The eighth chapter of the book deals with enantioselective cobalt-catalysed 1,2-nucleophilic additions to carbonyl compounds and derivatives, other than (nitro)-aldol reactions. These reactions have been promoted using various biphosphine cobalt catalysts and Werner complexes. Among the most efficient reactions, are additions of diisopropylzinc to pyrimidine-5-carbaldehyde, phenylboronic acids to substituted aldehydes, vinyl boronic acids to a range of activated carbonyl compounds and derivatives, and malonates or nitroalkanes to α-amido sulfones.
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