1.37 sample 
Portion of a material taken for qualitative analysis or quantitative analysis
 Note 1: Taking a sample from a larger amount of material implies the existence of a sampling error,12 i.e., the measured quantity values of the portion's properties are only estimates of those of the parent material. 
Note 2: If the portion is removed with negligible sampling error it is termed an aliquot, or specimen. “Specimen” is used to denote a portion taken under conditions such that the sampling variability cannot be assessed, and is assumed, for convenience, to be zero. 
Note 3: The sampling plan should detail how a sample is obtained and any subsequent manipulations (see sample pre-treatment). 
Note 4: Fundamentals of sampling and sample preparation in analytical chemistry are detailed in ref. 27 and 28. 
Note 5: In analytical chemistry ‘sample’ must not be confused with a subset of a population for which the term “sample” is used in statistics. 
See also: analytical sample, laboratory sample, primary sample, replicate sample, and spike
1.37 sample 
Portion of a material taken for qualitative analysis or quantitative analysis
 Note 1: Taking a sample from a larger amount of material implies the existence of a sampling error,12 i.e., the measured quantity values of the portion's properties are only estimates of those of the parent material. 
Note 2: If the portion is removed with negligible sampling error it is termed an aliquot, or specimen. “Specimen” is used to denote a portion taken under conditions such that the sampling variability cannot be assessed, and is assumed, for convenience, to be zero. 
Note 3: The sampling plan should detail how a sample is obtained and any subsequent manipulations (see sample pre-treatment). 
Note 4: Fundamentals of sampling and sample preparation in analytical chemistry are detailed in ref. 27 and 28. 
Note 5: In analytical chemistry ‘sample’ must not be confused with a subset of a population for which the term “sample” is used in statistics. 
See also: analytical sample, laboratory sample, primary sample, replicate sample, and spike

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