Figure 1.3
Absolute energy scale showing the redox Fermi levels of several redox couples. The figure also shows the positions of the conduction and valence bands of CdS, Fe2O3 and TiO2 in electrolytes with pH values equal for their respective pHpzc values: CdS – pH 2.0; Fe2O3 – pH 8.60. TiO2 – pH 4.30.15 At these pH values, the surface dipole associated with ionic states on the surface is assumed to be close to zero. Note that the band energies of the oxides are shifted upwards by increases in pH and downwards by decreases in pH.

Absolute energy scale showing the redox Fermi levels of several redox couples. The figure also shows the positions of the conduction and valence bands of CdS, Fe2O3 and TiO2 in electrolytes with pH values equal for their respective pHpzc values: CdS – pH 2.0; Fe2O3 – pH 8.60. TiO2 – pH 4.30.15  At these pH values, the surface dipole associated with ionic states on the surface is assumed to be close to zero. Note that the band energies of the oxides are shifted upwards by increases in pH and downwards by decreases in pH.

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