Figure 1.1
![IR-SEC of [Re(tBu-bpy)(CO)3Cl] (black, 2) under N2 in 0.1 M Bu4NPF6/MeCN, showing three major species as the potential is increased cathodically: ReI(tBu-bpy˙−)(CO)3Cl (red), Re0(tBu-bpy)(CO)3 (green), Re0 (tBu-bpy˙−)(CO)3 (blue). IR-SEC cell: Pt working electrode, Pt counter electrode, Ag pseudo-reference electrode. (B) Cyclic voltammogram of 2 under N2 in 0.1 M Bu4NPF6/MeCN (GC WE, Pt wire CE, Ag/AgCl pseudo-RE, with Fc added as an internal standard), showing correlation to species seen in IR-SEC. Y-axis is current density (J) and the x-axis is potential (V) vs. saturated calomel electrode (SCE). Reproduced from ref. 29 with permission from American Chemical Society, Copyright 2014.](https://rsc.silverchair-cdn.com/rsc/content_public/books/836/parts/bk9781788015462-00001/5/bk9781788015462-00001-f1.jpeg?Expires=1716483799&Signature=bw6zUKfKdGxQ6F-7hQI8U6CHSjXNjQfzgjbY5FNi77BdH2Y19hGc45Y4H0ABsNRoWqSyFh0zswWVzOLjuvdlsQPuGkZCxLaT1mgD5mz4KjmrMyicn3hVUi63kWd40-yZk~rpTDMjmmfNqwwXOJOGjdJkAFy3F2Kx4wLX92BRIr5UwwdZ80PsjGO4NqDUIi94RGujvf4G082JKbfYCm5TH0091hAvin~dl5KaXhdBpN6AmxiHu3y7NJtnwlmGAvuNr5jcKP~tEdrBfArLUSLNY8fYh1rFMQg1sngeipbZ-NBwxG0zJMPTwnNvEFTKImUDsuBcC~4bEYmw0lXaaOJbag__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
IR-SEC of [Re(tBu-bpy)(CO)3Cl] (black, 2) under N2 in 0.1 M Bu4NPF6/MeCN, showing three major species as the potential is increased cathodically: ReI(tBu-bpy˙−)(CO)3Cl (red), Re0(tBu-bpy)(CO)3 (green), Re0 (tBu-bpy˙−)(CO)3 (blue). IR-SEC cell: Pt working electrode, Pt counter electrode, Ag pseudo-reference electrode. (B) Cyclic voltammogram of 2 under N2 in 0.1 M Bu4NPF6/MeCN (GC WE, Pt wire CE, Ag/AgCl pseudo-RE, with Fc added as an internal standard), showing correlation to species seen in IR-SEC. Y-axis is current density (J) and the x-axis is potential (V) vs. saturated calomel electrode (SCE). Reproduced from ref. 29 with permission from American Chemical Society, Copyright 2014.
