Figure 1.1
Electrospray ionization (negative ions) and tandem mass spectrometry of common fatty acids as their carboxylate anions. (A) Product ions obtained following collisional activation of palmitic acid (16 : 0), m/z 255; (B) product ions obtained following collisional activation of stearic acid (18 : 0) [M − H]− at m/z 383; (C) product ions obtained following collisional activation of oleic acid (18 : 1, n-9) [M − H]− at m/z 281; (D) product ions obtained following collisional activation of docosahexaenoic acid (22 : 6, n-3) [M − H]− at m/z 327. These MS/MS spectra were obtained using a tandem quadrupole mass spectrometer.

Electrospray ionization (negative ions) and tandem mass spectrometry of common fatty acids as their carboxylate anions. (A) Product ions obtained following collisional activation of palmitic acid (16 : 0), m/z 255; (B) product ions obtained following collisional activation of stearic acid (18 : 0) [M − H] at m/z 383; (C) product ions obtained following collisional activation of oleic acid (18 : 1, n-9) [M − H] at m/z 281; (D) product ions obtained following collisional activation of docosahexaenoic acid (22 : 6, n-3) [M − H] at m/z 327. These MS/MS spectra were obtained using a tandem quadrupole mass spectrometer.

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